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Zinc Sulphate or Zinc Sulfate SDS MSDS Sheet of Suppliers

Anmol Chemicals is a manufacturer supplier exporter of Zinc Sulphate or Zinc Sulfate and it offers materials as per IP BP EP Ph Eur USP NF JP FCC Food Grade as per the the latest monograph at best prices. Anmol Chemicals Group, established in 1976, is the pioneer manufacturer of Specialty Chemicals, Pharmaceutical Excipients, Some API, Food Chemicals in India. Anmol Chemicals Group has manufacturing facilities spread across Western India, representatives in Houston, Chicago USA and Dubai, UAE. We also have toll manufacturing units for processing chemicals in a few countries around the world. We make IP, BP, EP, USP, NF, Ph. Eur., JP, FCC or Food Grade, Analytical Reagent Grade, LR or Laboratory Reagent Grades and Pure Grades of various chemicals. All our items are analyzed to meet the required standards. We can supply the product in grams for your laboratory trial and in tons for your plant scale jobs.

We manufacture Bulk Drugs / API, Excipients, Pharmaceuticals (IP BP USP NF Ph Eur EP JP), Specialty Chemicals (Pure/Reagent), Mineral Fortifiers (FCC). Our manufacturing facility is FDA approved and GLP, cGMP, ISO9001, ISO14001, ISO/IEC 17025, ISO22000, FSSC 22000, ISO45001, FSSAI, Kosher, HALAL, COPP, WHO-GMP certified and Written Confirmation (WC) is available. Solid materials can be customized for particle size, shape, and bulk density. We observe WHO Good Manufacturing Practices and Good Laboratory Practices. We are a government-recognized STAR Export House and "Authorised Economic Operator (AEO)" per Indian Customs.

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Zinc Sulphate Specifications of Suppliers

Zinc Sulphate

CAS Number: 7446-20-0 &7733-02-0, Molecular Weight: 287.54, Chemical Formula: ZnSO47H2O, EINECS EC Number: 231-793-3

Zinc Sulphate or Zinc Sulfate SDS Safety Data Sheet
MSDS, Material Safety Data Sheet

SECTION 1. PRODUCT IDENTIFICATION

Product Name & Other Names: Zinc Sulphate or Zinc Sulfate. It comes as heptahydrate, monohydrate and anhydrous.
CAS Number: 7446-19-7
EINECS EC Number: 231-793-3
Molecular Weight: 161.4 for anhydrous.
Chemical Formula: ZnSO4 for anhydrous.
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per the letterhead.

SECTION 2. HAZARDS IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity oral (Category 1), H302
Skin corrosion/irritation (Category 2), H315
Serious eye damage (Category 1), H318
Specific target organ toxicity, single exposure; Respiratory tract irritation (Category 3), H335
Hazardous to the aquatic environment, long-term hazard (Category 1), H410

Labeling according GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H302: Harmful if swallowed
H315: Causes skin irritation.
H318: Causes serious eye damage.
H335: May cause respiratory irritation.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P391: Collect spillage.
P501: Dispose of contents/ container to an approved waste disposal plant.

Classification according to European Directive 67/548/EEC as amended:
Hazard symbols:
Xn Harmful
C Corrosive
R-phrases:
R22 Harmful if swallowed.
R36/37 Irritating to eyes and respiratory system.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS

Product Name & Other Names: Zinc Sulphate or Zinc Sulfate. It comes as heptahydrate, monohydrate and anhydrous.
CAS Number: 7446-19-7
EINECS EC Number: 231-793-3

SECTION 4. FIRST AID MEASURES

Always seek medical attention after first aid measures are provided.

Eye Contact: Do not allow victim to rub eye (s). Let the eye (s) water naturally for a few minutes. If particle/dust does not dislodge, flush with lukewarm, gently flowing water for 5 minutes or until particle/dust is removed, while holding eyelid (s) open. If irritation persists, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye.
Skin Contact: Remove contaminated clothing, shoes, and leather goods (e.g. watchbands, belts). Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm gently flowing water and non-abrasive soap for 5 minutes. If irritation persists, repeat flushing. Obtain medical advice. Completely decontaminate clothing, shoes and leather goods before reuse or else discard.
Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. Obtain medical advice.
Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 2 – 8 oz. (60 – 240 ml) of water. Zinc sulfate is an emetic and may cause vomiting. If vomiting occurs naturally, have victim rinse mouth with water again. Obtain medical advice and bring a copy of this MSDS.

SECTION 5. FIRE FIGHTING MEASURES

Fire and Explosion Hazards: It does not burn or support combustion.
Extinguishing Media: Use any means of extinction appropriate for the surrounding fire conditions such as water spray, carbon dioxide, dry chemical, or foam.
Fire Fighting: Toxic fumes of sulfur dioxide may result from combustion. As with any fire, fire fighters should be fully trained and wear full protective clothing including an approved, self-contained breathing apparatus which supplies a positive air pressure within a full-face piece mask. Do not use water directly on material. Do not allow water run-off to enter sewers or watercourses.
Flashpoint and Method: Not Applicable.
Upper and Lower Flammable Limit: Not Applicable.
Auto ignition Temperature: Not Applicable.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: It is colorless, odorless granules or powder.
Odor: None.
Odor threshold: Not available.
pH: 4 to 6 @ 10% solution
Relative density: around 3.28 for heptahydrate.
Freezing/Melting Point/Range: Loses water at 238C; Decomposes at 680C (1256F)
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility in Water: Soluble in water. Aqueous solutions are acidic.
Viscosity: Not available.
Molecular Weight: 161.4 for anhydrous.
Chemical Formula: ZnSO4 for anhydrous.

SECTION 10. STABILITY AND REACTIVITY

Stability and Reactivity: Stable and not considered reactive under normal temperatures and pressures. Hazardous polymerization or runaway reactions will not occur.
Incompatibilities: Strong oxidizing agents. Avoid excessive heating.
Hazardous Decomposition Products: High temperature operations such as oxyacetylene cutting, electric arc welding or severe overheating will generate zinc oxide fume which, on inhalation in sufficient quantity, can produce metal fume fever. Under such conditions, sulfur dioxide will also be generated and can cause respiratory distress.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity (Oral LD50): > 574 mg/kg Rat
Acute Toxicity (Dermal LD50): > 2000 mg/kg Rat
General: In the form in which Zinc Sulphate is sold it is relatively non-toxic. The major route of exposure would be through the generation and inhalation of airborne dust and especially the generation of zinc oxide fume through thermal decomposition.
Acute:
Skin/Eye: Zinc Sulfate direct contact may cause local irritation of the eyes or skin but would not cause tissue damage. Eye contact with solutions (>1%) may cause the appearance of white flecks on the lens of the eye. Dust or fume from burning or welding operations may also cause local irritation.
Inhalation: Zinc Sulphate acute inhalation may result in irritation but is not expected to cause significant harmful effects. Symptoms may include discomfort, coughing, tingling sensation, sneezing and/or shortness of breath and wheezing. Extreme heating of Zinc Sulphate monohydrate will generate zinc oxide fume. If inhaled, this fume can result in the condition called metal fume fever. The symptoms of metal fume fever will occur within 3 to 10 hours of exposure, and include immediate dryness and irritation of the throat, tightness of the chest, and coughing which may later be followed by flu-like symptoms of fever, malaise, perspiration, frontal headache, muscle cramps, low back pain, occasionally blurred vision, nausea, and vomiting. The symptoms are temporary and generally disappear, without medical intervention, within 24 to 48 hours of onset. There are no recognized complications, after affects, or chronic affects that result from this condition.
Ingestion: Zinc Sulfate ingestion of large doses can cause anemia and stomach symptoms. It is very astringent, and when ingested in excessive quantities, can irritate the stomach, resulting in abdominal pain, nausea, diarrhea, and spontaneous vomiting.
Chronic: In general, zinc is a low toxicity metal. Zinc is an important trace element for humans and the body regulates the amount of zinc stored by decreasing absorption and increasing excretion when intake is increased. Industrial experience has not identified any significant chronic effects from zinc sulfate to date. The item is not listed as a carcinogen by the Occupational Safety and Health Administration (OSHA), the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC), the American Conference of Governmental Industrial Hygienists (ACGIH) or the European Union (EU).
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

SECTION 12. ECOLOGICAL INFORMATION

Eco toxicological data:
LC50 24 hours fish (rainbow trout) 1.24 mg/l
LC50 48 hours fish (rainbow trout) 2.4 - 5 mg/l
LC50 96 hours fish (rainbow trout) 0.24 - 0.83 mg/l
LC50 96 hours Daphnia 7.4 mg/l
Zinc Sulphate has high water solubility and its zinc content is directly bio available. The zinc may be toxic to aquatic organisms, especially fish, with water hardness, pH and dissolved organic carbon levels being regulating factors.

SECTION 13. DISPOSAL CONSIDERATIONS

Do not wash the material down drain. Put uncontaminated material back into the process if possible. Place contaminated material in suitable, labeled containers for disposal. Dispose of waste material consistent with the requirements of waste disposal authorities.

SECTION 14. TRANSPORT INFORMATION

DOT ADR/RID:
UN Number: 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc sulphate monohydrate)
Transport hazard class(es): 9; Packaging group: III
IATA:
UN Number: 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc sulphate monohydrate)
Transport hazard class(es): 9; Packaging group: III
IMDG:
UN Number: 3077
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Zinc sulphate monohydrate)
Transport hazard class(es): 9; Packaging group: III

SECTION 15. REGULATORY INFORMATION

USA Regulations:
SARA 313 toxic chemical notification and release reporting: Zinc sulfate monohydrate.
SARA 311/312: See section 2.

SECTION 16 - ADDITIONAL INFORMATION

European Labeling in Accordance with EC Directives:
H302 = Harmful if swallowed
H315 = Causes skin irritation.
H318 = Causes serious eye damage.
H335 = May cause respiratory irritation.
H410 = Very toxic to aquatic life with long lasting effects.

Classification according to European Directive 67/548/EEC as amended:
Hazard symbols:
Xn Harmful
C Corrosive
R-phrases:
R22 Harmful if swallowed.
R36/37 Irritating to eyes and respiratory system.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Disclaimer:
*********************************
Our company provides this Zinc Sulphate SDS sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Zinc Sulphate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
*********************************

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Manufacturers

ANMOL CHEMICALS
Taloja Mumbai and Ankleshwar, INDIA
Representatives in Houston, Chicago and New York, USA
TEL: (OFF) +91 22 23726950, +91 22 23774610, +91 22 23723564

e-mail: info@anmol.org

Copyright and Usual Disclaimer is Applicable
Last updated 23-dec-22

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